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dc.contributor.authorBarge, L.M.
dc.contributor.authorCardoso, S.S.S.
dc.contributor.authorCartwright, J.H.E.
dc.contributor.authorCooper, G.J.T.
dc.contributor.authorCronin, L.
dc.contributor.authorde Wit, A.
dc.contributor.authorDoloboff, I.J.
dc.contributor.authorEscribano, B.
dc.contributor.authorGoldstein, R.E.
dc.contributor.authorHaudin, F.
dc.contributor.authorJones, D.E.H.
dc.contributor.authorMackay, A.L.
dc.contributor.authorMaselko, J.
dc.contributor.authorPagano, J.J.
dc.contributor.authorPantaleone, J.
dc.contributor.authorRussell, M.J.
dc.contributor.authorSainz-Díaz, C.I.
dc.contributor.authorSteinbock, O.
dc.contributor.authorStone, D.A.
dc.contributor.authorTanimoto, Y.
dc.contributor.authorThomas, N.
dc.date.accessioned2016-06-13T13:32:22Z
dc.date.available2016-06-13T13:32:22Z
dc.date.issued2015-12-31
dc.identifier.issn0009-2665
dc.identifier.urihttp://hdl.handle.net/20.500.11824/172
dc.description.abstractChemical gardens in laboratory chemistries ranging from silicates to polyoxometalates, in applications ranging from corrosion products to the hydration of Portland cement, and in natural settings ranging from hydrothermal vents in the ocean depths to brinicles beneath sea ice. In many chemical-garden experiments, the structure forms as a solid seed of a soluble ionic compound dissolves in a solution containing another reactive ion. In general any alkali silicate solution can be used due to their high solubility at high pH. The cation should not precipitate with the counterion of the metal salt used as seed. A main property of seed chemical-garden experiments is that initially, when the fluid is not moving under buoyancy or osmosis, the delivery of the inner reactant is diffusion controlled. Another experimental technique that isolates one aspect of chemical-garden formation is to produce precipitation membranes between different aqueous solutions by introducing the two solutions on either side of an inert carrier matrix. Chemical gardens may be grown upon injection of solutions into a so-called Hele-Shaw cell, a quasi-two-dimensional reactor consisting in two parallel plates separated by a small gap.
dc.formatapplication/pdf
dc.language.isoengen_US
dc.rightsReconocimiento-NoComercial-CompartirIgual 3.0 Españaen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/es/en_US
dc.titleFrom chemical gardens to chemobrionics
dc.typeinfo:eu-repo/semantics/articleen_US
dc.identifier.doi10.1021/acs.chemrev.5b00014
dc.relation.publisherversionhttp://pubs.acs.org/doi/10.1021/acs.chemrev.5b00014
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen_US
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen_US
dc.journal.titleChemical Reviewsen_US


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Reconocimiento-NoComercial-CompartirIgual 3.0 España
Except where otherwise noted, this item's license is described as Reconocimiento-NoComercial-CompartirIgual 3.0 España